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51.
对于一般任意支撑的连续梁结构动力稳定性问题,已有的计算方法求解过程都很复杂,给工程设计带来极大的不便.本文提出了一个简化的分析方法,利用现有的商业软件,只需求得连续梁的自然频率及静力屈曲(失稳)荷载,就可容易得到结构的动力失稳区域,当考虑结构阻尼对不稳定区域的影响时,可将阻尼矩阵表达为Rayleigh阻尼的形式.研究结果表明:采用本文计算方法与已有的理论计算方法得到的连续梁主参数共振的不稳定边界非常吻合,而本文计算方法更为简单,计算结果可靠,计算精度高,可满足工程设计的需要. 相似文献
52.
利用固定点理论优化接地类型的动力吸振器得到的结果可能不是全局最优参数,在选择其他参数时主系统可以获得更小的振幅, 接地类型动力吸振器的优化问题值得进一步研究. 因此,以一种接地式三要素型动力吸振器为对象,通过研究系统参数变化对固 定点位置与主系统最大振幅的影响,得到了此吸振器的局部最优参数并分析了它的性能. 首先建立了此系统模型的运动微分方程, 得到了主系统振幅放大因子,发现系统存在3个与阻尼无关的固定点. 固定点中幅值较大点随系统参数变化的趋势可以代表最大振 幅随系统参数变化的趋势,因此利用盛金公式得到了固定点幅值的表达式. 为了更加精确,进一步使用数值算法得到了最大振幅与 系统参数的关系图,发现系统中存在局部最优参数. 通过对比接地式吸振器与接地三要素型吸振器的最大振幅随系统参数变化的趋 势,得到了接地式三要素型吸振器的局部最优参数,并发现当固有频率比小于局部最优频率比时,接地式三要素型吸振器模型主系 统的最大振幅要远小于接地式动力吸振器模型. 相似文献
53.
Basak Karpuz 《Mathematical Methods in the Applied Sciences》2019,42(9):2993-3001
In this paper, we give new sufficient conditions for both oscillation and nonoscillation of the delay dynamic equation where and satisfy τ(t) ≤ σ(t) for all large t and . As an important corollary, we obtain the time scale invariant integral condition for nonoscillation: for all large t. Also, with some examples, we show that newly presented results are sharp. 相似文献
54.
We study the integrality gap of the natural linear programming relaxation for the Bounded Color Matching (BCM) problem. We provide several families of instances and establish lower bounds on their integrality gaps and we study how the Sherali–Adams “lift-and-project” technique behaves on these instances. We complement these results by showing that if we exclude certain simple sub-structures from our input graphs, then the integrality gap of the natural linear formulation strictly improves. To prove this, we adapt for our purposes the results of Füredi (1981). We further leverage this to show upper bounds on the performance of the Sherali–Adams hierarchy when applied to the natural LP relaxation of the BCM problem. 相似文献
55.
56.
Dr. Dmitry B. Eremin Ekaterina A. Denisova Dr. Alexander Yu. Kostyukovich Dr. Jonathan Martens Dr. Giel Berden Prof. Dr. Jos Oomens Prof. Dr. Victor N. Khrustalev Prof. Dr. Victor M. Chernyshev Prof. Dr. Valentine P. Ananikov 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(72):16564-16572
N-Heterocyclic carbene (NHC) ligands are ubiquitously utilized in catalysis. A common catalyst design model assumes strong M–NHC binding in this metal–ligand framework. In contrast to this common assumption, we demonstrate here that lability and controlled cleavage of the M−NHC bond (rather than its stabilization) could be more important for high-performance catalysis at low catalyst concentrations. The present study reveals a dynamic stabilization mechanism with labile metal–NHC binding and [PdX3]−[NHC-R]+ ion pair formation. Access to reactive anionic palladium intermediates formed by dissociation of the NHC ligands and plausible stabilization of the molecular catalyst in solution by interaction with the [NHC-R]+ azolium ion is of particular importance for an efficient and recyclable catalyst. These ionic Pd/NHC complexes allowed for the first time the recycling of the complex in a well-defined form with isolation at each cycle. Computational investigation of the reaction mechanism confirms a facile formation of NHC-free anionic Pd in polar media through either Ph–NHC coupling or reversible H–NHC coupling. The present study formulates novel ideas for M/NHC catalyst design. 相似文献
57.
Umar Farid Maria Luisa Aiello Prof. Stephen J. Connon 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(43):10074-10079
A new catalytic methodology was developed to promote an efficient one-pot kinetic resolution of racemic aldehydes with selectivity (s*) of up to 91 (99:1 d.r., >99 % ee) in a cycloaddition reaction with enolizable anhydrides to afford dihydroisocoumarin products (a core prevalent in natural products and molecules of medicinal interest) containing three contiguous stereocentres. 相似文献
58.
59.
Michael Braun 《组合设计杂志》2019,27(11):682-687
An ‐arc in is a set of points such that each line contains at most of the selected points. It is well known that ‐arcs in correspond to projective linear codes. Let denote the maximal number of points for which an ‐arc in exists. In this paper we obtain improved lower bounds on by explicitly constructing ‐arcs. Some of the constructed ‐arcs correspond to linear codes meeting the Griesmer bound. All results are obtained by integer linear programming. 相似文献
60.
In single‐molecule force spectroscopy (SMFS), many studies have focused on the elasticity and conformation of polymer chains, but little attention has been devoted to the dynamic properties of single polymer chains. In this study, we measured the energy dissipation and elastic properties of single polystyrene (PS) chains in toluene, methanol, and N,N‐dimethylformamide using a homemade piezo‐control and data acquisition system externally coupled to a commercial atomic force microscope (AFM), which provided more accurate information regarding the dynamic properties of the PS chains. We quantitatively measured the chain length‐dependent changes in the stiffness and viscosity of a single chain using a phenomenological model consistent with the theory of viscoelasticity for polymer chains in dilute solution. The effective viscosity of a polymer chain can be determined using the Kirkwood model, which is independent of the intrinsic viscosity of the solvent and dependent on the interaction between the polymer and solvent. The results indicated that the viscosity of a single PS chain is dominated by the interaction between the polymer and solvent. © 2019 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2019 , 57, 1736–1743 相似文献